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two.2]decane core and defining the geometry from the exocyclic double bond. The activation energies of development of your vinyl-gold intermediates were calculated and uncovered a silyl enol ether with an unprotected indole moiety as an acceptable precursor with the Toste cyclization. This 6-step synthesis didn't entail any nonstrategic redox manip

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That is an open up-obtain post dispersed beneath the phrases from the Inventive Commons Attribution-NonCommercial 4.0 Worldwide License () which permits copy and redistribute the material just in noncommercial usages, supplied the original perform is correctly cited.The rankings reflect our viewpoint and may be a very good starting point for browsi

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